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The assembly, synthesis and properties of a trinuclear cyano-bridged CuII-MoIV-CuII complex

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A new trinuclear cyano-bridged CuII-MoIV-CuII compound has been prepared, characterized spectroscopically (UV-Vis and IR) and its structure determined by X-ray crystallography. The title complex 1 exhibits an antiferromagnetic exchange interaction between copper(II) ions mediated by [Mo(CN)8]4- diamagnetic units.

Keywords: Crystal structure; Cyano-bridged complex; Magnetic property

Document Type: Research Article

Affiliations: 1: Department of Chemistry, South China University of Technology, Guangzhou, China 2: Department of Chemistry, Luoyang Normal University, Luoyang, China

Publication date: 01 January 2008

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