@article {Wang:2007:0095-8972:1587,
title = "Synthesis, crystal structure and electrochemical behavior of di--{salicylidene-[1-(t-butyl)-5-methyl-1H-pyrazole]-formohydra-zino-4 O,N,O':O'}-nitratocopper(II)",
journal = "Journal of Coordination Chemistry",
parent_itemid = "infobike://tandf/gcoo",
publishercode ="tandf",
year = "2007",
volume = "60",
number = "14",
publication date ="2007-07-01T00:00:00",
pages = "1587-1594",
itemtype = "ARTICLE",
issn = "0095-8972",
eissn = "1029-0389",
url = "https://www.ingentaconnect.com/content/tandf/gcoo/2007/00000060/00000014/art00012",
doi = "doi:10.1080/00958970601089226",
keyword = "Crystal structure, Binuclear copper complex, Electrochemical behavior, Thermal analysis",
author = "Wang, Wei and Li, Xue-Mei and Meng, Xiang-Tao and Bi, Sai and Zhang, Shu-Sheng",
abstract = "The reaction of Cu(NO3)2 with salicylidene-[1-(t-butyl)-5-methyl-1H-pyrazole]-formohydrazine (Hsal-pfh, 1) gives a binuclear Cu(II) complex [Cu2(sal-pfh)2(NO3)2] (2). The structure of the ligand was characterized by IR, EA, 1H NMR spectroscopy. The binuclear Cu complex was determined by X-ray crystallography and thermal analysis. The two Cu(II) ions are bridged by two O atoms and each copper ion is surrounded by an asymmetric sal-pfh chromophore and a [image omitted] group. The coordination around each copper can be best described as a distorted square-pyramidal geometry. The electrochemical experimental results indicate that 2 can bind to DNA with good stability.",
}