The novel azomethine ligands for binuclear copper(II) complexes with ferro- and antiferromagnetic properties
A series of novel binuclear ferro- and antiferromagnetic Cu(2+) chelates of structurally broadly varied Schiff bases (derived from o-tosylamino(hydroxyl)benzaldehydes and monoalkylated o-phenylenediamine, o-aminophenol, o-aminothiophenol, 1,2-diaminobenzimidazole, 1-aminobenzimidazoline-2-thione) and -diketimines (derived from 2,6-di-i-Pr-aniline) has been prepared. The tautomerism of the ligands and structureof their copper complexes have been studied with the use of IR, 1H NMR EPR and EXAFS spectroscopy. Molecular and crystal structure of a -diketimine copper dimer has been determined by X-ray crystallography. The magnetic measurements (2-300 K) performed for all the complexes showed that the ferro- and antiferromagnetic character of the exchange interaction depends both on the structure of the coordination site (origin of the ligating centers) and the structure of the ligands (in particular, on the type of the cycle annelated to the bridging fragment). Whereas S-binding metal chelates 13 (X = NTs, Y = S, R = H) are diamagnetic, the complexes 15 with annelated azole moieties are ferromagnetic.
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Ferromagnetic and antiferromagnetic interaction;
Document Type: Research Article
Institute of Physical and Organic Chemistry of Rostov State University, 344090 Rostov-on-Don, Russian Federation
International Tomography Center, Siberian Branch of Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation
Southern Research Center of Russian Academy of Sciences, 344006 Rostov-on-Don, Russian Federation
A.N. Nesmeyanov Institute of Organoelement Compounds, 119991 Moscow, Russian Federation
Institute of Physics of Southern Federal University, 344090 Rostov-on-Don, Russian Federation
Rostov State Pedagogical University, 344010 Rostov-on-Don, Russian Federation
G.A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences, 603950 Nizhnii Novgorod, Russian Federation
Institute of Physical and Organic Chemistry of Rostov State University, 344090 Rostov-on-Don, Russian Federation,Southern Research Center of Russian Academy of Sciences, 344006 Rostov-on-Don, Russian Federation
July 1, 2007