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The crystal structure of octakispentoxy-phthalocyaninatocopper with pyridines axially substituted: the molecules stacked with J-aggregates

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For coordination with two pyridines at the axis, the ring skeleton of octakispentoxyphthalo- cyaninatocopper maintains planar conformation, different from the structure of octakisbutoxy- phthalocyaninatocopper reported previously. The structure shows all molecules stacked along the b axis to form a one-dimensional molecular chain; neighboring molecules in the chain are arranged as J-aggregates, consistent with its crystal diffuse reflectance spectroscopy (DRS) having a red shift compared with its electronic absorption spectroscopy in pyridine.
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Keywords: Crystal structure; J-aggregates; Substituted phthalocyanines

Document Type: Research Article

Affiliations: Institute of Research on Functional Materials, College of Chemistry and Chemical Engineering, Fuzhou University, and State Key Laboratory of Structural Chemistry, Fuzhou 350002, P.R. China

Publication date: July 1, 2007

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