Skip to main content
padlock icon - secure page this page is secure

Synthesis, crystal structure and magnetism of a three-dimensional Mn(II) coordination polymers with 2,5-dimethylpyrazine-1,4-dioxide as bridging ligand

Buy Article:

$60.00 + tax (Refund Policy)

A novel three-dimensional Mn(II) coordination polymer, {[Mn(1,6-dmpzdo)3] · (ClO4)2}n, has been synthesized with 2,5-dimethylpyrazine-1,4-dioxide (dmpzdo) as a bridging ligand and its crystal structure determined by X-ray crystallography. The complex crystallizes in a trigonal system with a space group R-3 and a = 11.6672(14), b = 11.6672(14), c = 16.652(4) Å. In the complex each Mn(II) is coordinated by six 1,6-dmpzdo bridging ligands and each 1,6-dmpzdo bridging ligand coordinates two Mn(II) ions, forming a three-dimensional structure. The variable temperature (4-300 K) magnetic susceptibility data gave the magnetic coupling constant 2J = -0.30 cm-1.
No Reference information available - sign in for access.
No Citation information available - sign in for access.
No Supplementary Data.
No Article Media
No Metrics

Keywords: Aromatic N-oxide; Crystal structure; Magnetism; Multi-nuclear complex

Document Type: Research Article

Affiliations: 1: Department of Chemistry, Shandong Normal University, Jinan 250014, P.R. China 2: Department of Chemistry, Nankai University, Tianjin 300071, P.R. China

Publication date: July 1, 2007

  • Access Key
  • Free content
  • Partial Free content
  • New content
  • Open access content
  • Partial Open access content
  • Subscribed content
  • Partial Subscribed content
  • Free trial content
Cookie Policy
X
Cookie Policy
Ingenta Connect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more