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A new capped iron(III) trinuclear benzoate cluster

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The new cluster [Fe3O(C7H5O2)6(phen)(H2O)]NO3 was prepared and characterized by atomic absorption, elemental analysis, mass spectrometry, Mössbauer, IR, UV-vis and EPR spectroscopies. Structural information was obtained from quantum mechanics calculations using the molecular mechanics (MM+) approach. This cluster has only one labile coordination site suitable for ligand substitution and can be used as a starting material to the rational assemble of polynuclear compounds.
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Keywords: Benzoate; Cluster; Iron(III); o-Phenanthroline

Document Type: Research Article

Affiliations: 1: Departamento de Química, Universidade Federal do Paraná, Curitiba, PR, Brasil 2: Department of Chemistry, Stanford University, Stanford, CA 94305-5080, USA 3: Department of Biological Chemistry, John Innes Centre, Norwich NR4 7UH, UK

Publication date: January 1, 2007

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