Skip to main content
padlock icon - secure page this page is secure

Chelate complexes from diphosphine substitution in pentakis(arylisocyanide)cobalt(I) complexes

Buy Article:

$60.00 + tax (Refund Policy)

Four chelate complexes, [Co(CNC6H3iPr2-2,6)3P(C6H4Me-p)2CH2CH2P(C6H4Me-p)2]BF4, [Co(CNC6H3iPr2-2,6)3PPh2CH=CHPPh2-cis]BF4, [Co(CNC6H3iPr2-2,6)3PPh2C6H4PPh2-o]BF4, and [Co(CNC6H3iPr2-2,6)3P(C6H4CF3-p)2CH2CH2P(C6H4CF3-p)2]BF4, have been synthesized by substitution reactions of [Co(CNC6H3iPr2-2,6)5]BF4 at elevated temperatures and/or prolonged reaction times. The complexes have been characterized by IR and electronic spectra, 31P NMR, cyclic voltammetry, and mass spectrometry. Comparisons are made with the pentakis(arylisocyanide)cobalt(I) complexes mono-substituted with diphosphine ligands.
No Reference information available - sign in for access.
No Citation information available - sign in for access.
No Supplementary Data.
No Article Media
No Metrics

Keywords: 31P-NMR; Arylisocyanide; Cobalt(I) complex; Cyclic voltammetry; Diphosphine

Document Type: Research Article

Affiliations: Department of Chemistry, University of Botswana, Gaborone, Botswana

Publication date: January 1, 2007

  • Access Key
  • Free content
  • Partial Free content
  • New content
  • Open access content
  • Partial Open access content
  • Subscribed content
  • Partial Subscribed content
  • Free trial content
Cookie Policy
X
Cookie Policy
Ingenta Connect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more