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Preparation and spectral investigation of bis[ N- (substituted-phenyl)thiobenzamidato]mercury(II) complexes

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Several preparative routes to bis[ N- (substituted-phenyl)thiobenzamidato]mercury(II) complexes are presented, including the reaction of mercury(II) oxide, fluoride, chloride, bromide, cyanide, acetal and nitrate with N- (substituted-phenyl)thiobenzamide derivatives. 1 H NMR, Raman and IR measurements confirm the complexation of mercury to sulfur. The mercury(II) complexes with N -substituted phenylthiobenzamide ligands did not show antimicrobial activity against test organisms, unlike the starting mercury(II) compounds of high toxicity. This may allow some therapeutic uses when considered as an antidote to mercury poisoning.
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Keywords: Mercury poisoning; Mercury(II); Thiobenzamide

Document Type: Research Article

Affiliations: 1: Department of Chemistry, University of Isfahan, Isfahan, Iran 2: Department of Chemistry, University of Ferdowsi, Mashhad, Iran 3: Department of Biology, University of Isfahan, Isfahan 81746, Iran

Publication date: July 20, 2005

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