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Synthesis, crystal structure and magnetic properties of a new complex containing Cu(I) and radicals, [Cu(imme2py)2](ClO4)

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A new complex, [Cu(imme2py)2](ClO4) (imme2py?=?2-(2'-(6'-methylpyridyl))-4,4,5,5-tetramethyl-1H-imidazolyl-1-oxyl) has been synthesized and structurally characterized by X-ray diffraction methods. It crystallizes in the orthorhombic crystal system, space group P 212121. The structure consists of [Cu(imme2py)2] + cations and chloride anions. The coordination geometry about Cu(I) is tetrahedral with the four coordination sites being occupied by four nitrogen atoms. Magnetic measurements show intramolecular antiferromagnetic interactions between the imino nitroxides.
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Keywords: Crystal structure; Cu(I) complex; Imino nitroxide; Magnetism

Document Type: Research Article

Affiliations: 1: State Key Laboratory of Coordination Chemistry, Nanjing, 210093, People's Republic of China 2: Department of Chemistry, NanKai University, Tianjin 300071, People's Republic of China

Publication date: July 20, 2005

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