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Hydrothermal synthesis and characterization of a novel polyoxometallate-templated three-dimensional supramolecular network

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The well-known polyoxomolybdate anion [Mo8O26]4− has been used as a noncoordinating anionic template for the construction of a novel three-dimensional (3D) supramolecular network, [Co(phen)3]2[Mo8O26]ยท 2.5H2O (1) (phen = o-phenanthroline). Compound 1 has been characterized by elemental analyses, IR spectrum, X-ray photoelectron spectroscopy (XPS), TG analysis and single-crystal X-ray diffraction. Single-crystal X-ray diffraction analysis reveals that [Co(phen)3]2+ coordination complexes are packed together via aromatic - stacking and hydrogen-bonding interactions, and exhibit an interesting 3D supramolecular network with one-dimensional (1D) box-like channels in which the octamolybdate anions reside.
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Keywords: Crystal structure; Hydrothermal synthesis; Octamolybdate; Supramolecular network

Document Type: Research Article

Publication date: May 1, 2004

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