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Complexation and mutagenicity potential studies with N, N′-bis(2-hydroxynaphthalin-1-carbaldehydene)-1,2-bis-(P-aminophenoxy)ethane and a novel oxovanadium(IV) complex

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A new oxovanadium(IV) complex of the Schiff base obtained by condensation of 1,2-bis(p-aminophenoxy)ethane with 2-hydroxynaphthalin-1-carbaldehyde was synthesized. The complex was characterized by elemental analysis, magnetic measurements, mass spectral data, UV-visible and IR spectra. Stability constants and thermodynamic values for complexation between Cu(NO3)2, Zn(NO3)2·6H2O, Ni(NO3)2·6H2O and VOSO4·5H2O and the ligand in 80% dioxane/water were determined by conductance measurements. Ni(II) and Cu(II) complexes of the ligand synthesized by a previously described method were found to be mutagens on strain TA 100 in the presence and absence of S9 mix. These compounds are classified as mutagenic in the Ames test.
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Keywords: Complexation studies; Mutagenic and Ames test; Oxovanadium(IV); Schiff-base complexes

Document Type: Research Article

Affiliations: 1: Chemistry Department Faculty of Education Dicle University Campus Diyarbakır Turkey 2: Chemistry Department Faculty of Arts and Sciences Balıkesir University Balıkesir Turkey 3: Biology Department Faculty of Arts and Sciences Dicle University Diyarbakır Turkey 4: Biology Department Faculty of Education Dicle University Campus Diyarbakır Turkey

Publication date: May 1, 2004

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