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Synthesis and crystal ctructure of trans-dichloro(1,3-propylenediamine-n,n′-diacetato)platinum(IV) monohydrate

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The trans-geometrical isomer of the first Pt(IV) complex with the tetradentate ligand 1,3-propylenediamine-N,N′-diacetate ion (pdda) was prepared by a direct synthesis from potassium hexachloroplatinate(IV) and pdda in the presence of lithium hydroxide. The crystal structure of trans-[Pt(pdda)Cl2]·H2O complex has been determined. The Pt(IV) ion has a distorted octahedral coordination due to intramolecular N-H···Cl interactions.
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Keywords: Crystal structure; Edda ligands; Platinum(IV) complex

Document Type: Research Article

Affiliations: 1: Faculty of Chemistry University of Belgrade P.O. Box 158 Studentski trg 16 11001 Belgrade Serbia and Montenegro 2: Laboratory of Theoretical Physics and Condensed Matter "VINČA" Institute of Nuclear Sciences P.O. Box 522 11001 Belgrade Serbia and Montenegro

Publication date: May 1, 2004

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