The trans-geometrical isomer of the first Pt(IV) complex with the tetradentate ligand 1,3-propylenediamine-N,N′-diacetate ion (pdda) was prepared by a direct synthesis from potassium hexachloroplatinate(IV) and pdda in the presence of lithium hydroxide. The crystal structure of trans-[Pt(pdda)Cl2]·H2O complex has been determined. The Pt(IV) ion has a distorted octahedral coordination due to intramolecular N-H···Cl interactions.
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Document Type: Research Article
Faculty of Chemistry University of Belgrade P.O. Box 158 Studentski trg 16 11001 Belgrade Serbia and Montenegro
Laboratory of Theoretical Physics and Condensed Matter "VINČA" Institute of Nuclear Sciences P.O. Box 522 11001 Belgrade Serbia and Montenegro
Publication date: May 1, 2004