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Synthesis and crystal structure of bis(dicyclohexylammonium) Tetracyanonickel(II)

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A novel, one-dimensional nickel(II) complex, [(C6H11)2NH2]2[Ni(CN)4], has been synthesized and structurally characterized by X-ray single crystallographic methods. The complex crystallizes in the triclinic, space group P1 with a = 9.237(1), b = 9.576(2), c = 9.689(3) Å, α = 61.51(2),  = 85.69(3),  = 74.27(2)°, V = 723.6(3) Å3, Z = 1. The square-planar Ni(II) centre of the cyanonickellate anion is four coordinated by cyanide ligands. The dicyclohexylammonium cation occupies a bridging position by hydrogen bonding to the cyanide ligand nitrogen atoms of adjacent anions.
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Keywords: Crystal structure; Cyanonickellate(II) complex; Dicyclohexylamine; Hydrogen bonding

Document Type: Research Article

Publication date: January 10, 2004

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