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1H NMR Spectra of Platinum(II) Complexes Containing Piperidine and Another Amine

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1H NMR spectra of a series of cis-[Pt(Pip)(Am)Cl2] complexes (Pip=piperidine, Am=another amine) have been recorded and analyzed. Spin-spin splitting patterns of nonequivalent protons , , , , , and of piperidine have been designated. The piperidine ring has a chair confirmation with the nitrogen atom bound to the Pt atom in an equatorial manner; the examined complexes have a cis-configuration, with the plane of aromatic amine and the piperidine ring perpendicular to the coordination plane of Pt(II).
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Keywords: 1H NMR; Piperidine; Platinum(II) complexes; cis-Diamine platinum(II)

Document Type: Research Article

Publication date: May 20, 2003

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