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Substituted imidazole copper(II) complexes: The coordination polymer complex tetrakis N-methylimidazole copper(II) sulfate

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Treatment of copper(II) sulfate with four equivalents of N-methylimidazole in dry methanol leads to isolation of tetrakis-N-methylimidazole copper(II) sulfate, [Cu(NMeim)4](SO4). X-ray quality crystals of the complex were isolated by evaporation. The complex crystallizes in the (No. 2) space group with a = 9.0754(6) Å, b = 9.9729(7) Å, c = 12.745(2) Å, α = 98.342(9)°, β = 95.367(9)°, γ = 114.153(5)°, Z = 2, V3) = 1026.3(4), R = 0.031 and R w = 0.038.
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Keywords: Copper; Imidazole; Methylimidazole; Structure; Synthesis

Document Type: Research Article

Publication date: May 20, 2003

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