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Palladium(II) Complexes of 1-vinylimidazole

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Two new co-ordination compounds of PdII with 1-vinylimidazole of the formulae [PdL4]Cl2·3H2O and trans-[PdL2Cl2], where L is a 1-vinylimidazole molecule, have been obtained. The compounds were characterised by spectroscopic, molar conductivity, thermogravimetric and magnetochemical measurements. Single crystal X-ray structure analyses of the complexes were also carried out. The compounds are diamagnetic with square-planar coordinatination around the palladium(II) ions. Other physico-chemical properties of the both complexes are compatible with their structures.
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Keywords: Crystal structure; Imidazole derivatives; Palladium(II) complexes; Spectra

Document Type: Research Article

Affiliations: Institute of Chemistry, Pedagogical University, Chęcin´ska 5, 25-020 Kielce, Poland

Publication date: January 1, 2002

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