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Synthesis and Crystal Structure of Complexes of Lanthanide Picrates With N,N′-Dimethyl-N,N′-Diphenyl-1,2-PhenylenediOxydiacetamide

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Lanthanide picrate complexes with the ligand N,N′-dimethyl-N,N′-diphenyl-1,2-phenylenedioxydiacetamide (L) [Ln(Pic)3L] (Ln=La,Gd,Er,Y) have been prepared in nonaqueous medium and characterized by elemental analysis, IR and 1H spectra. The Gd(III) complex [Gd(Pic)3L]ยท3CH3CN is triclinic, space group $P{\bar 1}$

Document Type: Research Article

Affiliations: Department of Chemistry, Lanzhou University, Lanzhou 730000, P.R. China

Publication date: 01 January 2002

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