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Synthesis and Crystal Structure of a Polymeric Heteronuclear Complex of Cadmium(II) and Silver(I)

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A polymeric complex of Cd(II) and Ag(I) bridged by thiocyanate and ethylenediamine, [Cd(en)1.5Ag(SCN)3], has been prepared and its structure determined by X-ray diffraction methods. The complex crystallizes in space group P21/n with a=7.456(1), b=9.915(2), c=19.822(2)Å, =98.94(1)°. The Cd(II) atom is octahedrally coordinated by three SCN anions and two en molecules, while the Ag(I) atom is tetrahedraly coordinated by four SCN anions. Both SCN anions and en molecules act as bridging ligands and link Ag(I) and Cd(II) atoms to form a three-dimensional polymeric structure. The distance between Ag(I) and the atom S of a 1,1,3-µ3-SCN anion is much longer than that between Ag(I) and the atom S of a 1,3-µ-SCN anion. The short ${\rm Ag {{\hskip -1pt -\!\!\!- \hskip-.5pt}} Ag}$
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Document Type: Research Article

Affiliations: Department of Chemistry, Zhejiang University, Hangzhou 310027, P.R. China

Publication date: January 1, 2002

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