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Tetracyanoquinodimethane Derivatives of Pentagonal Bipyramidal Complexes of Manganese(II), Iron(II), Nickel(II) and Copper(II) with 2,6-diacetylpyridinebis(semicarbazone): Single Crystal Structure of dichloro[2,6-diacetylpyridinebis (semicarbazone)] Manganese(II)monohydrate

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By using the donor ligand 2,6-diacetylpyridinebis(semicarbazone) (DAPSC), pentagonal bipyramidal complexes of Mn(II), Fe(II), Ni(II) and Cu(II) have been obtained. The structure of [MnCl2(DAPSC)]┬ĚH2O has been determined by X-ray crystallography. Further reactions of these complexes with lithium salts of 7,7′,8,8′-tetracyanoquinodimethane (TCNQ) yielded their corresponding adducts.
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Keywords: Charge transfer complex; Diacetylpyridine; Pentagonal bipyramidal; Semicarbazone; Tetracyanoquinodimethane

Document Type: Research Article

Affiliations: Department of Chemistry, Guru Nanak Dev University, Amritsar-143 005, India

Publication date: January 1, 2002

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