Analyses of Aluminum Structures in a Chinese Coal Ash and Its Slag by STMAS NMR
Double-quantum filter satellite-transition magic-angle spinning experiments were tentatively carried out by one high magnetic field solid-state nuclear magnetic resonance (800 MHz for 1H Larmor frequency) to analyze the local 27Al structure in minerals of coal
ash and slag. A high magnetic field offered higher sensitivity and resolution; hereby, the inconspicuous resonances of satellite-transition magic-angle spinning were obtained successfully at less stringent conditions. An obvious single 6-coordinate 27Al resonance was detected in
the low-temperature ash; structures in pre-molten ashes (as prepared at 815 and 1,000°C) located relatively integral and symmetric, while Al resonances in the ash prepared at 1,600°C after once completely molten demonstrated discrete and asymmetric distribution. Moreover, the detailed
spatial correlations among various aluminum species in rapid quenching slag exhibited dispersive T-O-T structures with lower signal-to-noise ratio of resonances.
Keywords: coal ash; gasification; mineral; solid-state nuclear magnetic resonance; structure
Document Type: Research Article
Affiliations: School of Chemical & Environmental Engineering, China University of Mining and Technology (Beijing), Beijing, P.R. China
Publication date: 02 October 2013
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