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Free Content Intermolecular and intramolecular transamidation reations

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The amide functional group is resonance stabilised and direct reaction with amines is known to be difficult. Facile amide exchange reactions would enable the synthesis of important new amide based molecules, therefore transamidation reactions represent an important step in this direction. In order to ensure a transamidation reaction takes place, special requirements and conditions are required. According to the different structural characteristics of the carboxamide group and types of activation, the most relevant examples of this reaction will be reviewed.
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Keywords: intermolecular and intramolecular transamidation reactions

Document Type: Journal Article

Affiliations: Department of Organic Chemistry, University of Valencia, Avda, Vicent Andrés Estellés s/n 46180-Burjassot, Valencia, Spain

Publication date: 10 August 2004

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  • Progress in Reaction Kinetics & Mechanism is an international journal for the quarterly publication of both in-depth reviews and research articles.

    In-depth reviews are comprehensive accounts bringing together work from many sources with the aim of providing an article of lasting value that will become established as the reference source in the particular subject. Research articles, on the other hand, normally focus on a relatively new or recently developed field or technique giving a state-of-the-art account of the subject and may well refer to a narrower range of existing work. It covers the fields of kinetics and mechanisms of chemical processes in the gas phase and solution of both simple and complex systems.

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