Skip to main content
padlock icon - secure page this page is secure

Open Access A Diiron Hydrogenase Mimic Featuring a 1,2,3-Triazolylidene

Download Article:
 Download
(PDF 421.2 kb)
 

This article is Open Access under the terms of the Creative Commons CC BY-NC licence.

A novel complex featuring a mesoionic carbene [Fe2(CO)5(trz)(μ-pdt)] (1) (trz = 1-phenyl-l,3-methyl,4-butyl-1,2,3-triazol-5-ylidene), was synthesized and spectroscopically and structurally characterized. The reductive behaviour of this compound in the presence and in the absence of acid (CH3CO2H) was examined by cyclic voltammetry (CV) that revealed the lack of efficient activity towards proton reduction.
No References for this article.
No Supplementary Data.
No Article Media
No Metrics

Keywords: BIOINSPIRED MODEL; DIIRON COMPLEX; HYDROGENASE; MESOIONIC CARBENE; PROTON REDUCTION

Document Type: Research Article

Affiliations: 1: Laboratoire de Chimie, Electrochimie Moléculaires et Chimie Analytique, UMR 6521 CNRS - Université de Bretagne Occidentale, CS 93837 - 6 Avenue Le Gorgeu, 29238 BREST Cedex 3 - France 2: Departement für Chemie und Biochemie, Universität Bern, Freiestrasse 3, CH-3012 Bern, Switzerland 3: Laboratoire de Chimie, Electrochimie Moléculaires et Chimie Analytique, UMR 6521 CNRS - Université de Bretagne Occidentale, CS 93837 - 6 Avenue Le Gorgeu, 29238 BREST Cedex 3 - France;, Email: [email protected]

Publication date: June 1, 2020

More about this publication?
  • International Journal for Chemistry and Official Membership Journal of the Swiss Chemical Society (SCS) and its Divisions

    CHIMIA, a scientific journal for chemistry in the broadest sense, is published 10 times a year and covers the interests of a wide and diverse readership. Contributions from all fields of chemistry and related areas are considered for publication in the form of Review Articles and Notes. A characteristic feature of CHIMIA are the thematic issues, each devoted to an area of great current significance.

  • Editorial Board
  • Information for Authors
  • Subscribe to this Title
  • Information for Advertisers
  • Ingenta Connect is not responsible for the content or availability of external websites
  • Access Key
  • Free content
  • Partial Free content
  • New content
  • Open access content
  • Partial Open access content
  • Subscribed content
  • Partial Subscribed content
  • Free trial content
Cookie Policy
X
Cookie Policy
Ingenta Connect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more