UVB-irradiated Laboratory-generated Secondary Organic Aerosol Extracts Have Increased Cloud Condensation Nuclei Abilities: Comparison with Dissolved Organic Matter and Implications for the Photomineralization Mechanism
During their atmospheric lifetime, organic compounds within aerosols are exposed to sunlight and undergo photochemical processing. This atmospheric aging process changes the ability of organic aerosols to form cloud droplets and consequently impacts aerosol–cloud interactions.
We recently reported changes in the cloud forming properties of aerosolized dissolved organic matter (DOM) due to a photomineralization mechanism, transforming high-molecular weight compounds in DOM into organic acids, CO and CO2. To strengthen the implications of this mechanism
to atmospheric aerosols, we now extend our previous dataset and report identical cloud activation experiments with laboratory-generated secondary organic aerosol (SOA) extracts. The SOA was produced from the oxidation of α-pinene and naphthalene, a representative biogenic and anthropogenic
source of SOA, respectively. Exposure of aqueous solutions of SOA to UVB irradiation increased the dried organic material's hygroscopicity and thus its ability to form cloud droplets, consistent with our previous observations for DOM. We propose that a photomineralization mechanism is also
at play in these SOA extracts. These results help to bridge the gap between DOM and SOA photochemistry by submitting two differently-sourced organic matter materials to identical experimental conditions for optimal comparison.
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CLOUD CONDENSATION NUCLEI;
DISSOLVED ORGANIC MATTER;
SECONDARY ORGANIC AEROSOL
Document Type: Research Article
Institute for Biogeochemistry and Pollutant Dynamics, ETH Zurich, Universitätstrasse 16, CH-8092 Zurich, Switzerland; Institute for Atmospheric and Climate Sciences, ETH Zurich, Universitatstrasse 16, CH-8092 Zurich, Switzerland;,
Email: [email protected]
Department of Chemistry, University of California, Irvine, 377 Rowland Hall, Irvine, USA
Institute for Biogeochemistry and Pollutant Dynamics, ETH Zurich, Universitätstrasse 16, CH-8092 Zurich, Switzerland
March 1, 2020
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International Journal for Chemistry and Official Membership Journal of the Swiss Chemical Society (SCS) and its Divisions
CHIMIA, a scientific journal for chemistry in the broadest sense, is published 10 times a year and covers the interests of a wide and diverse readership. Contributions from all fields of chemistry and related areas are considered for publication in the form of Review Articles and Notes. A characteristic feature of CHIMIA are the thematic issues, each devoted to an area of great current significance.
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