Skip to main content
padlock icon - secure page this page is secure

Open Access Cascades, Catalysis and Chiral Ligand Control with SmI2; The Rebirth of a Reagent

Download Article:
 Download
(PDF 391.6 kb)
 

This article is Open Access under the terms of the Creative Commons CC BY-NC licence.

This review focuses on recent developments from our laboratory in the field of radical reactions mediated by the archetypal reductive single electron transfer (SET) reagent, SmI2. Namely, we have expanded the scope of reducible carbonyl moieties to esters and amides and have exploited the resultant ketyl radicals in radical cascade reactions that generate unprecedented scaffolds. Moreover, we have taken the first steps to address the long-standing challenges of catalysis and chiral ligand control associated with the reagent.
No References for this article.
No Supplementary Data.
No Article Media
No Metrics

Keywords: ENANTIOSELECTIVE DESYMMETRISATION; RADICAL CASCADE; RADICAL RELAY CATALYSIS; SAMARIUM DIIODIDE

Document Type: Research Article

Affiliations: 1: Department of Chemistry, University of Manchester, Oxford Road, Manchester, M13 9PL, UK 2: Department of Chemistry, University of Manchester, Oxford Road, Manchester, M13 9PL, UK;, Email: [email protected]

Publication date: February 1, 2020

More about this publication?
  • International Journal for Chemistry and Official Membership Journal of the Swiss Chemical Society (SCS) and its Divisions

    CHIMIA, a scientific journal for chemistry in the broadest sense, is published 10 times a year and covers the interests of a wide and diverse readership. Contributions from all fields of chemistry and related areas are considered for publication in the form of Review Articles and Notes. A characteristic feature of CHIMIA are the thematic issues, each devoted to an area of great current significance.

  • Editorial Board
  • Information for Authors
  • Subscribe to this Title
  • Information for Advertisers
  • Ingenta Connect is not responsible for the content or availability of external websites
  • Access Key
  • Free content
  • Partial Free content
  • New content
  • Open access content
  • Partial Open access content
  • Subscribed content
  • Partial Subscribed content
  • Free trial content
Cookie Policy
X
Cookie Policy
Ingenta Connect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more