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Two-dimensional Polymers in Microscopy and Spatially Resolved Vibrational Analysis – A Review

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Two-dimensional polymers comprise a novel class of macromolecules with promising mechanical and chemical properties that have recently become accessible under mild synthetic conditions. As nanometer-sized holes and defects are likely to influence these materials' properties, there is a need for analytical methods to spatially and chemically characterize them down to the nanoscale. In this article, we compare tip-enhanced Raman spectroscopy to common methods in nanoanalysis for the investigation of defect sites in molecularly thin 2D-polymer sheets and briefly present measures to meet the challenges arising from tip-induced degradation processes.
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Keywords: 2D POLYMER; AFM; NANOMATERIALS; SPECTROSCOPY; STM; TERS

Document Type: Research Article

Affiliations: 1: Laboratory of Organic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zurich, Vladimir-Prelog-Weg 3, CH-8093 Zurich 2: Laboratory of Organic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zurich, Vladimir-Prelog-Weg 3, CH-8093 Zurich;, Email: [email protected]

Publication date: July 1, 2019

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  • International Journal for Chemistry and Official Membership Journal of the Swiss Chemical Society (SCS) and its Divisions

    CHIMIA, a scientific journal for chemistry in the broadest sense, is published 10 times a year and covers the interests of a wide and diverse readership. Contributions from all fields of chemistry and related areas are considered for publication in the form of Review Articles and Notes. A characteristic feature of CHIMIA are the thematic issues, each devoted to an area of great current significance.

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