Skip to main content
padlock icon - secure page this page is secure

Set Aside when Building the Periodic Table 150 Years ago, are Rare Earths any better considered by Chemists in the 21st Century?

Buy Article:

$25.00 + tax (Refund Policy)

A hundred and fifty years ago, the Rare Earths posed a serious problem to Mendeleyev because of their very similar chemical properties, although their atomic mass dispersions pointed to different elements. This difficulty persisted for several decades and only the emergence of the atomic theory provided some legiti- macy for their consideration as a full series of 15 elements resulting from the filling of the 4f orbitals (La-4f0 to Lu-4f14 ), to which scandium and yttrium were added for the sake of chemical similarities. However, it is difficult to give up bad habits and major advances in transition metal chemistry started systematically with d-block cations prior to extension to f-block analogues, and this despite the broader perspectives often brought by the latter. The technology-oriented society put in place for economic reasons during the last five decades has reactivated scientific interest in the Rare Earths, which have now become essential for many applications in telecommunications, lasers, magnetic materials and optical devices.
No Reference information available - sign in for access.
No Citation information available - sign in for access.
No Supplementary Data.
No Article Media
No Metrics

Keywords: 4F-SUBSHELL; LUMINESCENCE; MAGNETISM; RARE EARTHS

Document Type: Editorial

Affiliations: Department of Inorganic and Analytical Chemistry, University of Geneva 30 quai E. Ansermet, CH-1211 Geneva 4 ;, Email: [email protected]

Publication date: March 1, 2019

More about this publication?
  • International Journal for Chemistry and Official Membership Journal of the Swiss Chemical Society (SCS) and its Divisions

    CHIMIA, a scientific journal for chemistry in the broadest sense, is published 10 times a year and covers the interests of a wide and diverse readership. Contributions from all fields of chemistry and related areas are considered for publication in the form of Review Articles and Notes. A characteristic feature of CHIMIA are the thematic issues, each devoted to an area of great current significance.

  • Editorial Board
  • Information for Authors
  • Subscribe to this Title
  • Information for Advertisers
  • Ingenta Connect is not responsible for the content or availability of external websites
  • Access Key
  • Free content
  • Partial Free content
  • New content
  • Open access content
  • Partial Open access content
  • Subscribed content
  • Partial Subscribed content
  • Free trial content
Cookie Policy
X
Cookie Policy
Ingenta Connect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more