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Transition Metal-mediated Reactions in Biological Media

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Transition-metal catalysis has changed the way in which chemical reactions can be accomplished. While most metal-catalyzed reactions have been achieved in organic solvents, recent work has demonstrated that many of these transformations can be made compatible with water. These discoveries have stimulated the search for metal catalysts that are capable of achieving designed reactions in biological settings, and eventually behave as non-natural enzymes working in native cellular environments. Although this new field of research is still taking its first steps, there is a growing number of publications in the area, and one can predict that it will steadily grow in the years to come. Here we will briefly review some of the main contributions in the area. The contents have been organized according to the type of transformation and transition metal catalysts involved in the process.
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Keywords: ARTIFICIAL METALLOENZYMES; BIOORTHOGONAL; LIVING CELLS; ORGANOMETALLIC; TRANSITION METAL CATALYSIS

Document Type: Research Article

Affiliations: 1: Centro Singular de Investigación en Química Biolóxica e Materiais Moleculares (CIQUS) Departamento de Química Orgánica, Universidade de Santiago de Compostela, 15782 Santiago de Compostela, Spain;, Email: [email protected] 2: Centro Singular de Investigación en Química Biolóxica e Materiais Moleculares (CIQUS) Departamento de Química Orgánica, Universidade de Santiago de Compostela, 15782 Santiago de Compostela, Spain;, Email: [email protected]

Publication date: 01 November 2018

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  • International Journal for Chemistry and Official Membership Journal of the Swiss Chemical Society (SCS) and its Divisions

    CHIMIA, a scientific journal for chemistry in the broadest sense, is published 10 times a year and covers the interests of a wide and diverse readership. Contributions from all fields of chemistry and related areas are considered for publication in the form of Review Articles and Notes. A characteristic feature of CHIMIA are the thematic issues, each devoted to an area of great current significance.

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