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Synergistic Action of Copper Catalysts and Lewis Acids in Carbon–Carbon Bond Forming Reactions

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Combining Lewis acids with copper catalysis and highly reactive Grignard reagents allows fine tuning of the reactivity and selectivity of both inherently unreactive and highly reactive electrophilic substrates in asymmetric C–C bond forming reactions. In this review we will discuss various examples where the application of this strategy provides access to efficient catalytic processes for the synthesis of chiral molecules such as alcohols, amides and heteroarenes.
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Keywords: ALKYLATION; ASYMMETRIC CATALYSIS; COPPER; GRIGNARD REAGENTS; LEWIS ACID

Document Type: Research Article

Affiliations: 1: Synthetic Organic Chemistry Stratingh Institute for Chemistry University of Groningen Nijenborgh 4, Groningen, Netherlands 2: Synthetic Organic Chemistry Stratingh Institute for Chemistry University of Groningen Nijenborgh 4, Groningen, Netherlands;, Email: [email protected]

Publication date: 01 September 2018

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  • International Journal for Chemistry and Official Membership Journal of the Swiss Chemical Society (SCS) and its Divisions

    CHIMIA, a scientific journal for chemistry in the broadest sense, is published 10 times a year and covers the interests of a wide and diverse readership. Contributions from all fields of chemistry and related areas are considered for publication in the form of Review Articles and Notes. A characteristic feature of CHIMIA are the thematic issues, each devoted to an area of great current significance.

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