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Gold-catalyzed Dearomatization Reactions

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The advent of homogenous gold catalysis has revolutionized the way of approaching organic synthesis providing new and desirable solutions for challenging chemical manipulations of unactivated unsaturated hydrocarbons. In the realm of aromatic compounds, dearomatization protocols have been emerging as valuable synthetic tools to densely functionalized polycyclic 3D-molecular scaffolds, starting from readily available 2D-aromatic congeners. Gold catalysis contributed substantially in expanding this scenario enabling the condensation of numerous electron-rich arenes with hydrocarbons, resulting in the partial or total dearomatization of the aryl fragment. An overview of the most recent findings in the field, organized by type of electrophilic partners, is hereby presented.
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Document Type: Research Article

Affiliations: 1: Dipartimento di Chimica "G. Ciamician" Alma Mater Studiorum – Università di Bologna Via Selmi 2, Bologna, Italy 2: Dipartimento di Chimica "G. Ciamician" Alma Mater Studiorum – Università di Bologna Via Selmi 2, Bologna, Italy;, Email: [email protected]

Publication date: 01 September 2018

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  • International Journal for Chemistry and Official Membership Journal of the Swiss Chemical Society (SCS) and its Divisions

    CHIMIA, a scientific journal for chemistry in the broadest sense, is published 10 times a year and covers the interests of a wide and diverse readership. Contributions from all fields of chemistry and related areas are considered for publication in the form of Review Articles and Notes. A characteristic feature of CHIMIA are the thematic issues, each devoted to an area of great current significance.

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