Skip to main content
padlock icon - secure page this page is secure

New Directions in Transition Metal Catalyzed Carbonylation Chemistry

Buy Article:

$25.00 + tax (Refund Policy)

Carbon monoxide (CO) represents an important C1-building block for the construction of some of the most fundamental chemical functionalities carrying a carbon–oxygen double bond. Transition metal catalysis plays a key role in promoting such transformations. We have earlier shown that the combination of palladium catalysis with CO releasing molecules and the two-chamber reactor, COware, provides a convenient and safe means for performing traditional Pd-catalyzed carbonylative couplings, as well as being a platform for the discovery of new carbonylation reactions. Furthermore, the method can be adapted to 13C- and 14C-isotope labeling, as well as providing for a suitable setting for developing efficient carbonylation reactions with 11CO. Herein, we provide a short overview of our latest findings in this area with emphasis on carbonylative couplings with fluorinated building blocks, but also discuss our efforts to develop viable Ni-catalyzed carbonylations with aliphatic substrates, which can be performed efficiently under low CO partial pressures.
No Reference information available - sign in for access.
No Citation information available - sign in for access.
No Supplementary Data.
No Article Media
No Metrics

Keywords: CARBONYLATION; CATALYSIS; FLUORINATION; ISOTOPE LABELING; NICKEL; PALLADIUM

Document Type: Research Article

Affiliations: 1: Carbon Dioxide Activation Center (CADIAC) Interdisciplinary Nanoscience Center (iNANO) Department of Chemistry, Aarhus University Gustav Wieds Vej 14, 8000 Aarhus C, Denmark 2: Carbon Dioxide Activation Center (CADIAC) Interdisciplinary Nanoscience Center (iNANO) Department of Chemistry, Aarhus University Gustav Wieds Vej 14, 8000 Aarhus C, Denmark;, Email: [email protected]

Publication date: September 1, 2018

More about this publication?
  • International Journal for Chemistry and Official Membership Journal of the Swiss Chemical Society (SCS) and its Divisions

    CHIMIA, a scientific journal for chemistry in the broadest sense, is published 10 times a year and covers the interests of a wide and diverse readership. Contributions from all fields of chemistry and related areas are considered for publication in the form of Review Articles and Notes. A characteristic feature of CHIMIA are the thematic issues, each devoted to an area of great current significance.

  • Editorial Board
  • Information for Authors
  • Subscribe to this Title
  • Information for Advertisers
  • Ingenta Connect is not responsible for the content or availability of external websites
  • Access Key
  • Free content
  • Partial Free content
  • New content
  • Open access content
  • Partial Open access content
  • Subscribed content
  • Partial Subscribed content
  • Free trial content
Cookie Policy
X
Cookie Policy
Ingenta Connect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more