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Bioinspired Catalytic Generation of Main-group Electrophiles by Cooperative Bond Activation

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Catalytic processes involving cooperativity have seen tremendous progress in recent years and impressive new synthetic methodologies have been developed. Inspired by the cooperative heterolytic H2 splitting in [NiFe] hydrogenases, Ohki and Tatsumi designed cationic ruthenium thiolate complexes with a tethered sulfur ligand. Over the last decade, we have demonstrated the facile activation of main-group hydrides such as hydrosilanes, hydroboranes, DIBAL–H, and hydrostannanes by the Ru–S bond in Ohki–Tatsumi complexes. This account illustrates these E–H bond activations and highlights selected catalytic applications, particularly dehydrocouplings, of the generated main-group electrophiles.
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Keywords: COOPERATIVE CATALYSIS; C–H FUNCTIONALIZATION; DEHYDROGENATIVE COUPLINGS; MAIN-GROUP ELECTROPHILES

Document Type: Research Article

Affiliations: 1: Institut für Chemie Technische Universität Berlin Straße des 17. Juni 115, 10623 Berlin, Germany 2: Institut für Chemie Technische Universität Berlin Straße des 17. Juni 115, 10623 Berlin, Germany;, Email: [email protected]

Publication date: 01 September 2018

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  • International Journal for Chemistry and Official Membership Journal of the Swiss Chemical Society (SCS) and its Divisions

    CHIMIA, a scientific journal for chemistry in the broadest sense, is published 10 times a year and covers the interests of a wide and diverse readership. Contributions from all fields of chemistry and related areas are considered for publication in the form of Review Articles and Notes. A characteristic feature of CHIMIA are the thematic issues, each devoted to an area of great current significance.

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