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Open Access Original Reactivity of α-Diazo-β- ketoesters Catalyzed by CpRu Complexes

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Using α-diazo-β-ketoesters as reagents and combinations of CpRu fragments and diimine ligands as catalysts, a series of original transformations have been obtained that can be rationalized by the formation of metal carbenes and metal-bound ylide intermediates. Interesting 1,3-dioxole, enol-acetal and 1,4-dioxene motifs are obtained directly when the reactive mixture is reacted in presence of aldehydes or ketones, THF and epoxides.

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Keywords: DIAZO COMPOUNDS; INSERTIONS; METAL CARBENES; OXONIUM YLIDE

Document Type: Research Article

Affiliations: 1: University of Geneva Department of Chemistry Quai Ernest Ansermet 30 CH-1211 Geneva, Switzerland 2: University of Geneva Department of Chemistry Quai Ernest Ansermet 30 CH-1211 Geneva, Switzerland. [email protected]

Publication date: April 1, 2014

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  • International Journal for Chemistry and Official Membership Journal of the Swiss Chemical Society (SCS) and its Divisions

    CHIMIA, a scientific journal for chemistry in the broadest sense, is published 10 times a year and covers the interests of a wide and diverse readership. Contributions from all fields of chemistry and related areas are considered for publication in the form of Review Articles and Notes. A characteristic feature of CHIMIA are the thematic issues, each devoted to an area of great current significance.

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