The generation and study of 'cold' gas-phase molecules characterised by very low translational temperatures T
trans ≤ 1 K is an upcoming field of research in physical chemistry which has received considerable attention over the past years. A particular interesting
form of cold molecules are ensembles of cold localised cations in ion traps which form ordered structures known as 'Coulomb crystals'. The present article reviews the experimental methods used for the generation of atomic and molecular Coulomb crystals and highlights recent experiments which
take advantage of their intriguing properties in order to study chemical reactions at very low temperatures with single-particle sensitivity.
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Document Type: Research Article
February 1, 2009
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International Journal for Chemistry and Official Membership Journal of the Swiss Chemical Society (SCS) and its Divisions
CHIMIA, a scientific journal for chemistry in the broadest sense, is published 10 times a year and covers the interests of a wide and diverse readership. Contributions from all fields of chemistry and related areas are considered for publication in the form of Review Articles and Notes. A characteristic feature of CHIMIA are the thematic issues, each devoted to an area of great current significance.
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