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Open Access Platinum Group Metal Chemistry of Functionalised Phosphines

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Tertiary phosphines are a large class of fascinating ligands commonly used in platinum group metal (pgm) coordination chemistry. They play an important role in areas ranging from homogeneous catalysis to selective metal extraction chemistry and to therapeutic applications. In this article, pgm-containing complexes of new functionalised mono-, di- and polytertiary phosphines, derived from straightforward condensation reactions, are reviewed. These phosphines have been used as building blocks in supramolecular chemistry and for constructing novel hexanuclear pgm complexes, as ligands for bridging homo- and heterobimetallic late transition metals, and in the field of precious metal-based catalysis.

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Document Type: Research Article

Publication date: October 1, 2008

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