Skip to main content
padlock icon - secure page this page is secure

Open Access Iridium Compounds in Homogeneous Hydrogenation

Download Article:
 Download
(HTML 20.3 kb)
 
or
 Download
(PDF 293.9 kb)
 
Iridium is generally considered to be a less effective catalyst than the other platinum metals but when highly co-ordinatively unsaturated species of it are prepared they appear to be exceptionally active hydrogenation catalysts, even for reduction of sterically hindered olefins. A mechanism for this reaction has been postulated based on low temperature magnetic resonance evidence. As the reaction proceeds, catalytically inactive hydrogen bridged cluster compounds are formed but work is in progress to counter this deactivation by physically separating the catalytic centres on a polymer support.
No References for this article.
No Supplementary Data.
No Article Media
No Metrics

Document Type: Research Article

Publication date: October 1, 1978

More about this publication?
  • Access Key
  • Free content
  • Partial Free content
  • New content
  • Open access content
  • Partial Open access content
  • Subscribed content
  • Partial Subscribed content
  • Free trial content
Cookie Policy
X
Cookie Policy
Ingenta Connect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more