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P‐containing polyaryloxydiphenylsilanes as flame retardants

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Polyaryloxydiphenylsilanes were prepared from phosphorus‐containing diols and diphenydichlorolsilane through solution polymerization. With a stoichiometric imbalance in feed monomers, the resulting polymers exhibited moderate melting points and good processing properties. The polymers prepared showed initial decomposition temperatures above 340 °C, excellent thermal stability, high char yields at 850 °C and very high limited oxygen index values of 56–59. The polymers' char yields and their (P + Si) contents showed linear relationships.

© 2003 Society of Chemical Industry
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Keywords: flame retardance; phosphorus; polysilanes; thermal properties

Document Type: Research Article

Affiliations: 1: Department of Chemical Engineering and R&D Centre for Membrane Technology, Chung Yuan Christian University, Chungli, Taoyuan 320, Taiwan, Republic of China 2: R&D Department, Hsinchu Factory, Chang Chun Plastics Co, Huko, Hsinchu 303, Taiwan, Republic of China

Publication date: August 1, 2003

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