Skip to main content
padlock icon - secure page this page is secure

Open Access The crystal structures of iron and cobalt pyridine (py)–sulfates, [Fe(SO4)(py)4]n and [Co3(SO4)3(py)11]n

Download Article:

The full text article is available externally.

The article you have requested is supplied via the DOAJ. View from original source.

The solid-state structures of two metal–pyridine–sulfate compounds, namely catena-poly[[tetrakis(pyridine-κN)iron(II)]-μ-sulfato-κ2O:O′], [Fe(SO4)(C5H5N)4]n, (1), and catena-poly[[tetrakis(pyridine-κN)cobalt(II)]-μ-sulfato-κ2O:O′-[tetrakis(pyridine-κN)cobalt(II)]-μ-sulfato-κ3O,O′:O′′-[tris(pyridine-κN)cobalt(II)]-μ-sulfato-κ2O:O′], [Co3(SO4)3(C5H5N)11]n, (2), are reported. The iron compound (1) displays a polymeric structure, with infinite chains of FeII atoms adopting octahedral N4O2 coordination environments that involve four pyridine ligands and two bridging sulfate ligands. The cobalt compound (2) displays a polymeric structure, with infinite chains of CoII atoms. Two of the three Co centers have an octahedral N4O2 coordination environment that involves four pyridine ligands and two bridging sulfate ligands. The third Co center has an octahedral N3O3 coordination environment that involves three pyridine ligands, and two bridging sulfate ligands with one sulfate chelating the cobalt atom.
No References
No Citations
No Supplementary Data
No Article Media
No Metrics

Document Type: Research Article

Affiliations: Department of Chemistry and Biochemistry, University of Massachusetts Dartmouth, 285 Old Westport Road, North Dartmouth, MA 02747, USA

Publication date: January 1, 2018

  • Access Key
  • Free content
  • Partial Free content
  • New content
  • Open access content
  • Partial Open access content
  • Subscribed content
  • Partial Subscribed content
  • Free trial content
Cookie Policy
X
Cookie Policy
Ingenta Connect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more