@article {Takeshi:2018:2056-9890:825,
title = "Crystal structure of ()-(R,E)-3-(1,3-benzodioxol-5-yl)-5-[(4S,5R)-5-hydroxymethyl-2,2-dimethyl-1,3-dioxolan-4-yl]-N,N-dimethylpent-4-enamide",
journal = "Acta Crystallographica Section E: Crystallographic Communications",
parent_itemid = "infobike://doaj/20569890",
publishercode ="doaj",
year = "2018",
volume = "74",
number = "6",
publication date ="2018-01-01T00:00:00",
pages = "825-828",
itemtype = "ARTICLE",
issn = "2056-9890",
url = "https://www.ingentaconnect.com/content/doaj/20569890/2018/00000074/00000006/art00014",
doi = "doi:10.1107/S2056989018007132",
author = "Takeshi Oishi and Koki Ishii and Mizuki Ishibashi and Takaaki Sato and Noritaka Chida",
abstract = "In the title compound, C20H27NO6, the amide moiety is essentially planar, with a maximum deviation of 0.073(3), and one of the N-methyl groups shows rotational disorder. The five-membered 1,3-dioxolane ring adopts an envelope form, with the C atom bonded to the olefin side chain as the flap, which deviates from the mean plane through the other four atoms by 0.564(7). The 1,3-dioxole ring fused to the benzene ring adopts a flattened envelope form, with the C atom between the two O atoms as the flap, which deviates from the mean plane through the other four atoms by 0.215(7). The CC=CC olefin moiety is essentially planar and makes a dihedral angle of 87.1(3) with the benzene ring. An intramolecular OH...O hydrogen bond supports the molecular conformation, enclosing an S(11) graph-set motif. In the crystal, intermolecular CH...O hydrogen bonding links the molecules into a tape running along the b axis. Furthermore, other weak CH...O hydrogen bonds and a CH... interaction connect the tapes into a sheet structure parallel to (100).",
}