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Open Access Undecacarbonyl[(4-methylsulfanylphenyl)diphenylphosphane]triruthenium(0): crystal structure and Hirshfeld surface analysis

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The title cluster compound, [Ru3(C19H17PS)(CO)11], comprises a triangle of Ru0 atoms, two of which are bonded to four carbonyl ligands. The third metal atom is bound to three carbonyl ligands and the phosphane-P atom of a dissymmetric phosphane ligand, PPh2(C6H4SMe-4); no Ru...S interactions are observed. The phosphane occupies an equatorial position and its proximity to an Ru—Ru edge results in the elongation of this bond with respect to the others [2.8933 (2) Å cf. 2.8575 (2) and 2.8594 (3) Å]. In the crystal, phenyl-C—H...O(carbonyl) and carbonyl-O...O(carbonyl) [2.817 (2) Å] interactions combine to form a supramolecular chain propagating along [111]; the chains pack without directional interactions between them. The carbonyl-O...O(carbonyl) and other weak contacts have an influence upon the Hirshfeld surfaces with O...H contacts making the greatest contribution, i.e. 37.4% cf. 15.8% for O...O and 15.6% for H...H contacts.
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Document Type: Research Article

Affiliations: 1: Chemical Sciences Programme, School of Distance Education, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia 2: Department of Chemistry, Alzaiem Alazhari University, 1933, Khartoum, Sudan 3: Department of Physics, Bhavan's Sheth R. A. College of Science, Ahmedabad, Gujarat 380001, India 4: Research Centre for Crystalline Materials, School of Science and Technology, Sunway University, 47500 Bandar Sunway, Selangor Darul Ehsan, Malaysia

Publication date: January 1, 2018

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