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Open Access Crystal structure of bis(pyridine-4-carbothioamide-κN1)bis(thiocyanato-κN)cobalt(II) methanol monosolvate

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The asymmetric unit of the title compound, [Co(NCS)2(C6H6NS)4]·CH3OH, consists of one cobalt(II) cation, two thiocyanate anions, four pyridine-4-carbothioamide ligands and one methanol molecule that are located in general positions. The CoII cations are coordinated by two terminal N-bonding thiocyanate anions and four N-bonding pyridine-4-carbothioamide ligands, resulting in discrete and slightly distorted octahedral complexes. These complexes are linked into a three-dimensional network via intermolecular N—H...S hydrogen bonding between the amino H atoms and the thiocyanate and pyridine-4-carbothioamide S atoms. From this arrangement, channels are formed in which the methanol solvate molecules are embedded and linked to the host structure by intermolecular O—H...S and N—H...O hydrogen bonding.
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Document Type: Research Article

Affiliations: Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth Strasse 2, D-24118 Kiel, Germany

Publication date: January 1, 2017

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