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Open Access Synthesis, crystal structure and Hirshfeld surface analysis of a polymeric bismuthate(III) halide complex, (C6H6N3)2[BiCl5]·2H2O

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The synthesis and the crystal structure of a new halide-bridged polymer, namely catena-poly[bis(1,2,3-benzotriazolium) [[tetrachloridobismuth(III)]-μ-chlorido] dihydrate], {(C6H6N3)2[BiCl5]·2H2O}n are reported. The structure comprises polyanionic zigzag chains of formula [(BiCl5)2−]n running along the c-axis direction. The 1,2,3-benzotriazolium cations are linked between these polymer chains, via the water molecules, giving rise to left- and right-handed helical chains. Hirshfeld surface analysis and fingerprint plots were used to decode the intermolecular interactions in the crystal network and determine the contribution of the component units for the construction of the three-dimensional architecture.
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Document Type: Research Article

Affiliations: 1: Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte, Tunisia 2: Department of Chemical and Pharmaceutical Sciences, Centre for Structural, Diffractometry, University of Ferrara, Via L. Borsari 46, I-44121 Ferrara, Italy

Publication date: January 1, 2017

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