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Open Access Hybrid organic–inorganic crystal structure of 4-(dimethylamino)pyridinium dimethylammonium tetrachloridolead(II)

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The title compound, (C2H8N)(C7H11N2)[PbCl4], is a hybrid organic–inorganic material. It crystallizes in the space group C2/c and contains one half of a molecule of lead chloride, 4-(dimethylamino)pyridinium, and dimethylammonium in the asymmetric unit. The crystal structure exhibits chains of lead chloride capped by 4-(dimethylamino)pyridinium and dimethylammoium by hydrogen bonding. This creates a one-dimensional zipper-like structure down the a axis. The crystal structure is examined and compared to a similar structure containing lead chloride and dimethylbenzene-1,4-diaminium.
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Document Type: Research Article

Affiliations: 1: 730 Natural Sciences Complex, Buffalo, 14260-3000, USA 2: 771 Natural Sciences Complex, Buffalo, 14260-3000, USA

Publication date: January 1, 2017

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