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Open Access Crystal structure of poly[diaquabis(μ5-benzene-1,3-dicarboxylato)(N,N-dimethylformamide)cadmium(II)disodium(I)]

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The title compound, [CdNa2(C8H4O4)2(C3H7NO)(H2O)2]n or [CdNa2(1,3-bdc)2(DMF)(H2O)2]n, is a new CdII–NaI heterobimetallic coordination polymer. The asymmetric unit consists of one CdII atom, two NaI atoms, two 1,3-bdc ligands, two coordinated water molecules and one coordinated DMF molecule. The CdII atom exhibits a seven-coordinate geometry, while the NaI atoms can be considered to be pentacoordinate. The metal ions and their symmetry-related equivalents are connected via chelating–bridging carboxylate groups of the 1,3-bdc ligands to generate a three-dimensional framework. In the crystal, there are classical O—H...O hydrogen bonds involving the coordinated water molecules and the 1,3-bdc carboxylate groups and π–π stacking between the benzene rings of the 1,3-bdc ligands present within the frameworks.
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Document Type: Research Article

Affiliations: 1: Department of Chemistry, Faculty of Science and Technology, Thammasat University, Khlong Laung, Pathumthani 12121, Thailand 2: Materials and Textile Technology, Faculty of Science and Technology, Thammasat University, Khlong Laung, Pathumthani 12121, Thailand

Publication date: January 1, 2017

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