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Open Access Crystal structure of methyl 1-allyl-4-methyl-1H-benzo[c][1,2]thiazine-3-carboxylate 2,2-dioxide

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In the title compound, C14H15NO4S, the dihydrothiazine ring adopts a distorted sofa conformation with the S atom displaced from the mean plane through the N and C ring atoms by 0.767 (1) Å. The allyl substituent (C—C=C) is inclined to this mean plane by 78.5 (7)° and the acetate group [C(=O)—O—C] by 66.5 (3)°. In the crystal, molecules are linked by C—H...π interactions forming chains propagating along the a-axis direction.
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Document Type: Research Article

Affiliations: 1: National Polytechnic Institute, CIITEC, Cerrada Cecati S/N, Colonia Santa Catarina de Azcapotzalco, CP 02250, Mexico, DF, Mexico 2: SSI `Institute for Single Crystals', National Academy of Sciences of Ukraine, 60 Lenina Avenue, Kharkiv 61001, Ukraine 3: National University of Pharmacy, 4 Blyukhera St., Kharkiv 61168, Ukraine 4: Mexican Institute of Petroleum, Eje Central Lazaro Cardenas Norte 152, Col. San Bartolo Atepehuacan, 07730 Mexico, DF, Mexico

Publication date: January 1, 2016

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