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Open Access Synthesis, characterization and crystal structure of a 2-(diethylaminomethyl)indole ligated dimethylaluminium complex

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The title compound, [Al(CH3)2(C13H17N2)] (systematic name; {2-[(diethylamino)methyl]indol-1-yl-κ2N,N′}dimethylaluminium), was prepared by methane elimination from the reaction of 2-(diethylaminomethyl)indole and trimethylaluminium. The complex crystallizes readily from a concentrated toluene solution in high yield. The asymmetric unit contains two crystallographically independent molecules. Each molecule has a four-coordinate aluminium atom that has pseudo-tetrahedral geometry. C—H...π interactions link the independent molecules into chains extending along the b-axis direction.
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Document Type: Research Article

Affiliations: Department of Chemistry and Biochemistry, 556 MSB, 303 E. Kearsley, Flint, MI 48502, USA

Publication date: January 1, 2015

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