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Open Access Crystal structure of di-μ-isobutyrato-κ4O:O′-bis[cis-dichlorido(dimethyl sulfoxide-κS)rhenium(III)]

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The title compound, [Re2(C3H7COO)2Cl4{(CH3)2SO}2], comprises binuclear complex molecules [Re—Re = 2.24502 (13) Å] involving cis-oriented double carboxylate bridges, four equatorial chloride ions and two weakly bonded O atoms from dimethyl sulfoxide ligands in the axial positions at the ReIII atoms. In the crystal, molecules are linked into corrugated layers parallel to (101) by very weak C—H...Cl and C—H...O hydrogen-bonding interactions. C—H...Cl hydrogen bonding provides the links between layers to consolidate a three-dimensional framework.
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Document Type: Research Article

Affiliations: Department of Inorganic Chemistry, Ukrainian State University of Chemical Technology, Gagarin Ave. 8, Dnipropetrovsk 49005, Ukraine

Publication date: January 1, 2015

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