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Open Access Crystal structure of bis[μ-(4-methoxyphenyl)methanethiolato-κ2S:S]bis[chlorido(η6-1-isopropyl-4-methylbenzene)ruthenium(II)] chloroform disolvate

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The molecular structure of the title complex, [Ru2(C8H9OS)2Cl2(C10H14)2]·2CHCl3 or (p-MeC6H4Pri)2Ru2(SCH2-p-C6H5-OCH3)2Cl2·2CHCl3, shows inversion symmetry. The two symmetry-related RuII atoms are bridged by two 4-methoxy-α-toluenethiolato [(4-methoxyphenyl)methanethiolato] units. One chlorido ligand and the p-cymene ligand complete the typical piano-stool coordination environment of the RuII atom. In the crystal, the CH moiety of the chloroform molecule interacts with the chlorido ligand of the dinuclear complex, while one Cl atom of the solvent interacts more weakly with the methyl group of the bridging 4-methoxy-α-toluenethiolato unit. This assembly leads to the formation of supramolecular chains extending parallel to [021].
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Document Type: Research Article

Affiliations: Institut de Chimie, Université de Neuchâtel, Avenue de Bellevaux 51, CH-2000 Neuchâtel, Switzerland

Publication date: January 1, 2015

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