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Open Access Crystal structure of (μ-4-hydroxybenzenethiolato-κ2S:S)bis(μ-phenylmethanethiolato-κ2S:S)bis[(η6-1-isopropyl-4-methylbenzene)ruthenium(II)] tetrafluoridoborate

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The crystal structure of the dinuclear arene ruthenium title complex, [Ru2(C6H5OS)(C7H7S)2(C10H14)2]BF4, shows the two RuII atoms to be bridged by two benzylthiophenolate units and one 4-hydroxythiophenolate unit, with the remaining three coordination sites of each RuII atom being occupied by p-cymene ligands, completing the typical piano-stool coordination geometry. The BF4− counter-anion is surrounded by four cationic dinuclear complexes, showing an O—H...F hydrogen bond and several weak C—H...F interactions. This is the first example of an X-ray analysis of a mixed dinuclear trithiolate arene ruthenium(II) complex.
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Document Type: Research Article

Affiliations: Institut de Chimie, Université de Neuchâtel, Avenue de Bellevaux 51, CH-2000 Neuchâtel, Switzerland

Publication date: January 1, 2015

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