Skip to main content
padlock icon - secure page this page is secure

Open Access Crystal structure of [μ2-1,1′-bis(diphenylphosphanyl)ferrocene-κ2P:P′]bis[(pyrrolidine-1-carbodithioato-κS)gold(I)]

Download Article:

The full text article is available externally.

The article you have requested is supplied via the DOAJ. View from original source.

This article is Open Access under the terms of the Creative Commons CC BY licence.

The asymmetric unit of the title compound, {(C34H28FeP2)[Au(C5H8NS2)]2}, comprises half a molecule, with the full molecule being generated by the application of a centre of inversion. The independent AuI atom is coordinated by thiolate S and phosphane P atoms that define an approximate linear geometry [S—Au—P = 169.35 (3)°]. The deviation from the ideal linear is traced to the close approach of the (intramolecular) non-coordinating thione S atom [Au...S = 3.1538 (8) Å]. Supramolecular layers parallel to (100) feature in the crystal packing, being sustained by phenyl–thione C—H...S interactions, with the non-coordinating thione S atom in the role of a dual acceptor. Layers stack with no specific interactions between them.
No References
No Citations
No Supplementary Data
No Article Media
No Metrics

Document Type: Research Article

Affiliations: Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia

Publication date: January 1, 2015

  • Access Key
  • Free content
  • Partial Free content
  • New content
  • Open access content
  • Partial Open access content
  • Subscribed content
  • Partial Subscribed content
  • Free trial content
Cookie Policy
Cookie Policy
Ingenta Connect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more