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Open Access Crystal structure of bis(2-methyl-1H-imidazol-3-ium) tetrachloridocobaltate(II)

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The asymmetric unit of the title compound, (C4H7N2)2[CoCl4], consists of two 2-methylimidazolium cations and one tetrahedral [CoCl4]2− anion. The anions and cations interact through N—H...Cl hydrogen bonds to define layers with a stacking direction along [100]. Besides van der Waals forces, weak C—H...Cl interactions between these layers stabilize the crystal packing.
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Document Type: Research Article

Affiliations: 1: Laboratoire de Chimie Minérale et Analytique, Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, Sénégal 2: Département de Chimie, Université de Montréal, 2900 Boulevard Édouard-Montpetit, Montréal, Québec, H3C 3J7, Canada

Publication date: January 1, 2015

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